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New Heritage Pickup - 1922-D NGC MS-64 Peace With Color

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It's definitely an extremely interesting piece. However, when I see coins with splotchy toning like that, I wonder if missing pieces of the original toning might have flaked off in a microscopic or submicroscopic way somewhere along the line? The second question I have is what environmental conditions do you suppose were responsible for that toning, .... regardless of how you might respond to my first question. Thanks for any explanation.

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